Speaking of Benoit, his best matches? I really like some of his Japan stuff.
I think it's WAY too many to list. I'll just go with his WWE matches and try to name the absolute best only.
vs The Rock (Fully Loaded 00 + every other match)
vs Chris Jericho (SummerSlam 00, Royal Rumble 01)
vs Kurt Angle (Wrestlemania 17, Backlash 01, Royal Rumble 03)
w/ Jericho vs 2 Man Power Trip (Raw)
vs Stone Cold (Smackdown)
vs RVD (SummerSlam 02)
w/ Angle vs Edge & Mysterio (No Mercy 02)
vs Eddie Guerrero (Vengeance 03)
vs Brock Lesnar (Smackdown)
vs HBK (Raw x2)
vs HHH vs HBK (Wrestlemania 20, Backlash 04)
vs HHH (Ironman on Raw and Pick Your Poison 05)
vs Kane (Bad Blood 04)
vs Randy Orton (SummerSlam 04, Smackdown 06)
MITB I (WM21)
vs Regal (Velocity & No Mercy 06)
vs Edge (Raw after WM, Backlash 05 & Smackdown 07)
vs Finlay (Judgment Day 06)
I'm really bitter that he and Undertaker never worked a real program together.
Also opinions on Benoit's match with Sting on Nitro 99? I watched it the other day and it was pretty good.