The first set coming out before Benoit murdered himself, family and career meant that we got TLC III in all its awesomeness, so that set is an instant win.
Yes sir it did. He's even on the cover IIRC. Such an awesome set. So many matches I had forgotten like Christian vs Chris Jericho, Benoit vs Jericho, Edge vs Christian along with the TLC goodies and you have a ball with that jawn.
TLC IV is good, nothing great though. 8th best TLC match. Ranked them after watching TLC PPV:
13. Edge Vs Kane Vs Rey Mysterio Vs Alberto Del Rio - TLC XI TLC 2010 - **
12. Undertaker Vs Edge - TLC VII One Night Stand 2008 - **1/2
11. DX Vs JeriShow - TLC IX TLC 2009 - **1/2
10. CM Punk Vs Alberto Del Rio Vs The Miz - TLC XII TLC 2011 - **1/2
09. John Cena Vs Edge - TLC VI Unforgiven 2006 - ***
08. Bubba & Spike Vs Kane & Hurricane Vs Chris Jericho & Christian Vs Jeff Hardy & Rob Van Dam - TLC IV Raw 07/10/2002 - ***1/4
07. CM Punk Vs Jeff Hardy - TLC VIII SummerSlam 2009 - ***1/2
06. Jerry Lawler Vs The Miz - TLC X Raw 29/11/2010 - ***1/2
05. The Dudley Boys Vs The Hardy Boys Vs Edge & Christian - TLC II WrestleMania 01/04/2001 - ***3/4
04. Edge Vs Ric Flair - TLC V Raw 16/01/2006 - ***3/4
03. The Shield Vs Team Hell No & Ryback - TLC XIII TLC 2012 - ****
02. The Dudley Boys Vs The Hardy Boys Vs Edge & Christian - TLC I SummerSlam 2000 - ****1/4
01. The Dudley Boys Vs The Hardy Boys Vs Edge & Christian Vs Chris Jericho & Chris Benoit - TLC III Smackdown 24/05/2001 - ****1/2