That Austin/Benoit is really good. Probably the second best WWF TV match of 2000. Other than the big 5-on-5 in February I can't think of anything clearly better.
Favourite single brand PPV is probably Judgment Day 2006.
I might like the Austin/Angle match from the week after a little better than the Benoit match, not sure though, would have to watch em both back to back.